Freshman Organic Chemistry II .. - YaleCourses

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1. Mechanism: How Energies and Kinetic Order Influence Reaction Rates
1. Mechanism: How Energies and Kinetic Order Influence Reaction Rates
YaleCourses
00:49:00
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2. Peculiar Rate Laws, Bond Dissociation Energies, and Relative Reactivities
2. Peculiar Rate Laws, Bond Dissociation Energies, and Relative Reactivities
YaleCourses
00:48:14
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3. Rate and Selectivity in Radical-Chain Reactions
3. Rate and Selectivity in Radical-Chain Reactions
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00:46:46
4
4. Electronegativity, Bond Strength, Electrostatics, and Non-Bonded Interactions
4. Electronegativity, Bond Strength, Electrostatics, and Non-Bonded Interactions
YaleCourses
00:50:08
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5. Solvation, H-Bonding, and Ionophores
5. Solvation, H-Bonding, and Ionophores
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00:47:10
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6. Brønsted Acidity and the Generality of Nucleophilic Substitution
6. Brønsted Acidity and the Generality of Nucleophilic Substitution
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00:46:47
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7. Nucleophilic Substitution Tools - Stereochemistry, Rate Law, Substrate, Nucleophile
7. Nucleophilic Substitution Tools - Stereochemistry, Rate Law, Substrate, Nucleophile
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00:51:56
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8. Solvent, Leaving Group, Bridgehead Substitution, and Pentavalent Carbon
8. Solvent, Leaving Group, Bridgehead Substitution, and Pentavalent Carbon
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00:48:27
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9. Pentavalent Carbon? E2, SN1, E1
9. Pentavalent Carbon? E2, SN1, E1
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00:48:05
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10. Cation Intermediates. Alkenes: Formation, Addition, and Stability
10. Cation Intermediates. Alkenes: Formation, Addition, and Stability
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00:51:15
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11. Carbocations and the Mechanism of Electrophilic Addition to Alkenes and Alkynes
11. Carbocations and the Mechanism of Electrophilic Addition to Alkenes and Alkynes
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00:52:08
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12. Nucleophilic Participation During Electrophilic Addition to Alkenes
12. Nucleophilic Participation During Electrophilic Addition to Alkenes
YaleCourses
00:49:05
13
13. Addition to Form Three-Membered Rings: Carbenoids and Epoxidation
13. Addition to Form Three-Membered Rings: Carbenoids and Epoxidation
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00:50:55
14
14. Epoxide Opening, Dipolar Cycloaddition, and Ozonolysis
14. Epoxide Opening, Dipolar Cycloaddition, and Ozonolysis
YaleCourses
00:49:39
15
15. Metals and Catalysis in Alkene Oxidation, Hydrogenation, Metathesis, and Polymerization
15. Metals and Catalysis in Alkene Oxidation, Hydrogenation, Metathesis, and Polymerization
YaleCourses
00:50:36
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16. Isoprenoids, Rubber, and Tuning Polymer Properties
16. Isoprenoids, Rubber, and Tuning Polymer Properties
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00:46:27
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17. Alkynes. Conjugation in Allylic Intermediates and Dienes
17. Alkynes. Conjugation in Allylic Intermediates and Dienes
YaleCourses
00:49:38
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18. Linear and Cyclic Conjugation Theory. 4n+2 Aromaticity
18. Linear and Cyclic Conjugation Theory. 4n+2 Aromaticity
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00:47:46
19
19. Aromatic Transition States: Cycloaddition and Electrocyclic Reactions
19. Aromatic Transition States: Cycloaddition and Electrocyclic Reactions
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00:49:13
20
20. Electronic and Vibrational Spectroscopy
20. Electronic and Vibrational Spectroscopy
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00:49:47
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21. Functional Groups and Fingerprints in IR Spectroscopy. Precession of Magnetic Nuclei
21. Functional Groups and Fingerprints in IR Spectroscopy. Precession of Magnetic Nuclei
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00:53:39
22
22. Medical MRI and Chemical NMR
22. Medical MRI and Chemical NMR
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00:49:21
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23. Diamagnetic Anisotropy and Spin-Spin Splitting
23. Diamagnetic Anisotropy and Spin-Spin Splitting
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00:48:20
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24. Higher-Order Effects, Dynamics, and the NMR Time Scale
24. Higher-Order Effects, Dynamics, and the NMR Time Scale
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00:51:13
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25. C-13 and 2D NMR. Electrophilic Aromatic Substitution
25. C-13 and 2D NMR. Electrophilic Aromatic Substitution
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00:50:29
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26. Aromatic Substitution in Synthesis: Friedel-Crafts and Moses Gomberg
26. Aromatic Substitution in Synthesis: Friedel-Crafts and Moses Gomberg
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00:50:49
27
27. Triphenylmethyl and an Introduction to Carbonyl Chemistry
27. Triphenylmethyl and an Introduction to Carbonyl Chemistry
YaleCourses
00:45:34
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28. Mechanism and Equilibrium of Carbonyl Reactions
28. Mechanism and Equilibrium of Carbonyl Reactions
YaleCourses
00:49:04
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29. Imines and Enamines. Oxidation and Reduction
29. Imines and Enamines. Oxidation and Reduction
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00:50:02
30. Oxidation States and Mechanisms
30. Oxidation States and Mechanisms
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00:46:58
31
31. Periodate Cleavage, Retrosynthesis, and Green Chemistry
31. Periodate Cleavage, Retrosynthesis, and Green Chemistry
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00:46:08
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32. Measuring Bond Energies: Guest Lecture by Prof. G. Barney Ellison
32. Measuring Bond Energies: Guest Lecture by Prof. G. Barney Ellison
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00:47:33
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33. Green Chemistry. Acids and Acid Derivatives
33. Green Chemistry. Acids and Acid Derivatives
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00:49:20
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34. Acids and Acid Derivatives
34. Acids and Acid Derivatives
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00:50:29
35
35. Acyl Insertions and [gr]α-Reactivity
35. Acyl Insertions and [gr]α-Reactivity
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00:48:49
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36. [gr]α-Reactivity and Condensation Reactions
36. [gr]α-Reactivity and Condensation Reactions
YaleCourses
00:53:07
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37. Proving the Configuration of Glucose and Synthesizing Two Unnatural Products
37. Proving the Configuration of Glucose and Synthesizing Two Unnatural Products
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00:54:47
38
38. Review: Synthesis of Cortisone
38. Review: Synthesis of Cortisone
YaleCourses
00:52:09

30. Oxidation States and Mechanisms

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Freshman Organic Chemistry II (CHEM 125B)

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⁣Module 1 - Lecture 3 - Dynamic Force Analysis of Mechanisms
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⁣Mod-01 Lec-28 First passage and First return prob. Classification of states.
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⁣Lecture - 11 Oxidation I - Kinetics of Oxidation
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⁣Density of States
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⁣Density of States
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⁣Mod-01 Lec-38 Mechanisms Causing Instabilities and Strategies for Avoiding Combustion Instability
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⁣Mod-01 Lec-38 Mechanisms Causing Instabilities and Strategies for Avoiding Combustion Instability
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⁣Mod-01 Lec-23 Layering: thermal oxidation
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⁣Mod-01 Lec-39 Oxide structure and Oxidation
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